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Is it possible to walk/hike from Pienza to Montepulciano

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I am planning to hike from Pienza to Montepulciano, for taking the picture along the road, as I am attracted by the rolling hills, poppies field, wheat field...etc, all the typical Tuscany scenic view I can see there.

However, I don't have a car license, so I am planning to hike this route by walking along road SS146. And I can't find any advise from the internet.

So I am here to ask about the possibility about my planning:

My base is at Siena, I will depart from siena in the morning.
Arrive Pienza at 8:30, and walk around.
Start hiking from Pienza at 10:30. Walk along road SS146 and shoot photos.
Arrived Montepulciano at 15:30, and walk around the town.
Take the bus to Siena at 17:45.

Or if there any other good suggestions?

Thank you very much :D

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