Château de Grotteaux
It would be hard to dream up a more graceful assemblage of setting, buildings, and decor than that at this elegant countryside bed-and-breakfast set in a beautifully refurbished and exquisitely decorated 18th-century château in the golden triangle between Blois, Chambord, and Cheverny. Your gracious hosts have thought of everything, from the inviting interiors—done up in an oh-so-chic mix of antique and contemporary—to the luxury bedding. Guest rooms offer meticulously restored period frescos and floor-to-ceiling windows, with lovely views of the river and giant bathrooms. Because there are only five rooms (as well as a private apartment), guests feel totally at home and are free to roam the grounds and gardens (complete with an Eiffel bridge), swim in the heated pool, play tennis, or fish in the nearby river. There is no restaurant, but the owners are delighted to arrange meals at the château from a local Michelin-starred chef. It's also within biking distance of the major Loire châteaux, but good luck tearing yourself away.