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Wendy, In April it's ususally between 6:15 to 6:30 when the sun sets on Grand Cayman. I try to make dinner reservations at 6pm so I can watch the sunset while dining.
We just returned Saturday from a week on Grand Cayman and the sun was setting at 6:25pm. Since days are getting longer I would imagine it will be later than that!!
Looks like it might not change too much as we were there in may and it was definitely around 6:30. We made most of our dinner reservations to enjoy it.